Amphibian is Greek twice over: amphi, "of both kinds," plus bios, "life" — something that lives a double life. The ph in both halves is the standard way Latin transliterated the Greek letter phi, and English kept it rather than writing the f it actually says. That single detail is enough to place the word: English had a perfectly serviceable f and declined to use it, which almost always means the word came through Greek.
The meaning has narrowed sharply. When English took the word in the 1630s it meant simply "having two modes of existence," and could also mean "of doubtful nature" — an insult as much as a description. Zoologists then used it for any animal at home in both water and on land, which swept in crocodiles, seals, beavers, walruses and hippopotamuses. Only in 1835 was it pinned down to the modern class sitting between fishes and reptiles, the creatures that begin life in water with gills and finish it on land.
amphibian (adj.) 1630s, "having two modes of existence; of doubtful nature," from Greek amphibia , neuter plural of amphibios "living a double life," from amphi "of both kinds" (see amphi- ) + bios "life" (from PIE root *gwei- "to live"). Formerly used by zoologists to describe any sort of animal at home on land and in the water, including crocodiles, walruses, beavers, seals, hippopotamuses; the restriction to the class of animals between fishes and reptiles with life cycles that begin in water and mature on land is from 1835. also from 1630s amphibian (n.) "one of the class of animals between fishes and reptiles, having gills and living in water in the early stage of life, later living on land," 1835; from amphibian (adj.). Amphibia was used in this sense from c. 1600. also from 1835
amphibian came in through Greek, and its spelling follows that family's conventions.
How that family writes these sounds
| /f/ | ph, transliterating φ. English had a perfectly good f and pointedly didn't use itphotograph, philosophy, sphere, amphibian |
What gives it away on the page
| ph | Transliterates φ. English had a perfectly good f and didn't use it — that's the tell.photograph, philosophy, sphere, amphibian |